Some discussion then: https://news.ycombinator.com/item?id=32969413
[0] https://www.slashgear.com/motorola-lapdock-100-review-311918...
I recently bought a rare model variant that someone tried to make look better, maybe with a black marker/paint that was a solvent for the original paint/coating. It was pretty much ruined for office use, unless you transplanted it to a different shell, or you sandblasted off the sticky mess.
Also, the most common Unfortunate eBay Trick in the last few years seems to be to spray out the insides of electronics with Febreeze and related products. (Source: majority of a dozen used ThinkPads in the last few years, as well as a 3090, and a high-end PSU.) One of the recent ThinkPads, I think they might've used insecticide spray or bug repellent instead.
(ProTip: Never tell an eBay seller, "Don't worry, I already left positive feedback, but can you please just tell me what spray product that odor is from, so that I can use the right method to clean it out?" You will never hear back from that seller, like they have no incentive once positive feedback is left, or they are exercising their right to remain silent on the advice of their attorney.)
The usual culprit is that someone (faux-) rich has used cheap cologne on their singular golfing junket of the year, and I guess they sprayed it on their clothes after dressing, rather than their skin where it would count.
So if a garment can pass the smell-test in the thrift store, I have a better chance that I can tolerate it in my closet, or wearing it on my person. Not a guarantee, but a better chance!
I suspect it's a more common household item the seller happens to have on hand, and/or they're trying to mask/neutralize an odor (marijuana, tobacco, pets, garage/basement odors, etc.).
For professional resellers not operating out of their home, they might still be trying to get rid of odors in items they source, and maybe it's a lot worse since Covid WFH. (Also, I've heard of e-cyclers needing to use precautions for roaches and bed bugs.)
don't worry, the shock wears off eventually.
Separately, plasticizers incorporated in many plastics ("new car smell") often continue evaporating at smellable levels for decades.
I've sometimes wondered if it is just the chemicals breaking down as you describe, or even something like fungal metabolites.
Bad news about the former is it's an autocatalyzing reaction, once it gets going there's no stopping it. The good news about the later is it's relatively easy to scrub off using >95% IPA and a kitchen sponge.
If the latter, is it worth saving?